4-히드로키시페니르아세트아르데히드오키심모노오키시게나제

4-히드로키시페니르아세트아르데히드오키심모노오키시게나제
식별자
EC번호	1.14.13.68
데이터 베이스
IntEnz	IntEnz view
BRENDA	BRENDA entry
ExPASy	NiceZyme view
KEGG	KEGG entry
MetaCyc	metabolic pathway
PRIAM	profile
PDB 구조	RCSB PDB PDBe PDBj PDBsum
유전자 온트로지	AmiGO / EGO
검색 PMC articles PubMed articles NCBI proteins

4-히드로키시페니르아세트아르데히드오키심모노오키시게나제(4-hydroxyphenylacetaldehyde oxime monooxygenase)는, 시아노아미노산대사 효소의 하나로, 다음 화학반응을 촉매 하는 산화 환원 효소이다.

(Z)-4-히드록시 페닐 어셋알데히드 옥심+ NADPH + H⁺ + O₂ ${\displaystyle \rightleftharpoons }$ (S)-4-히드로키시만데로니트릴+ NADP⁺ + 2 H₂O

이 효소의 기질은(Z)-4-히드록시 페닐 어셋알데히드 옥심과 NADPH, H⁺ 및 O₂로, 생성물은(S)-4-히드로키시만데로니트릴과 NADP⁺, H₂O이다.

조직명은(Z)-4-hydroxyphenylacetaldehyde oxime, NADPH:oxygen oxidoreductase로, 별명에 4-hydroxybenzeneacetaldehyde oxime monooxygenase, cytochrome P₄₅₀II-dependent monooxygenase, NADPH-cytochrome P₄₅₀ reductase (CYP71E1), CYP71E1, 4-hydroxyphenylacetaldehyde oxime, NADPH:oxygen oxidoreductase가 있다.

참고 문헌

• MacFarlane IJ, Lees EM, Conn EE (1975). "The in vitro biosynthesis of dhurrin, the cyanogenic glycoside of Sorghum bicolor". J. Biol. Chem. 250 (12): 4708□13. PMID 237909. 
• Shimada M, Conn EE (1977). "The enzymatic conversion of p-hydroxyphenylacetaldoxime to p-hydroxymandelonitrile". Arch. Biochem. Biophys. 180 (1): 199–207. doi:10.1016/0003-9861(77)90026-1. PMID 193443. 
• Busk PK, Moller BL (2002). "Dhurrin synthesis in sorghum is regulated at the transcriptional level and induced by nitrogen fertilization in older plants". Plant. Physiol. 129 (3): 1222–31. doi:10.1104/pp. 000687. PMC 166516. PMID 12114576. http://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=166516. 
• BL, Bak S; Morant, M; Olsen, CE; Ekstrom, CT; Galbraith, DW; Moller, BL; Bak, S (2005). "Metabolic engineering of dhurrin in transgenic Arabidopsis plants with marginal inadvertent effects on the metabolome and transcriptome". Proc. Natl. Acad. Sci. U. S. A. 102 (5): 1779–84. doi:10.1073/pnas. 0409233102. PMC 545087. PMID 15665094. http://www.pubmedcentral.nih.gov/articlerender.fcgi?tool=pmcentrez&artid=545087. 

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